Uncertainty in simulated groundwater-quality trends in transient flow     

J. Jeffrey Starn  Amvrossios C. Bagtzoglou  Gary A. Robbins 《Hydrogeology Journal》2013,21(4):813-827

In numerical modeling of groundwater flow, the result of a given solution method is affected by the way in which transient flow conditions and geologic heterogeneity are simulated. An algorithm is demonstrated that simulates breakthrough curves at a pumping well by convolution-based particle tracking in a transient flow field for several synthetic basin-scale aquifers. In comparison to grid-based (Eulerian) methods, the particle (Lagrangian) method is better able to capture multimodal breakthrough caused by changes in pumping at the well, although the particle method may be apparently nonlinear because of the discrete nature of particle arrival times. Trial-and-error choice of number of particles and release times can perhaps overcome the apparent nonlinearity. Heterogeneous aquifer properties tend to smooth the effects of transient pumping, making it difficult to separate their effects in parameter estimation. Porosity, a new parameter added for advective transport, can be accurately estimated using both grid-based and particle-based methods, but predictions can be highly uncertain, even in the simple, nonreactive case.  相似文献   

Radio-colouration of diamond: a spectroscopic study     

Lutz Nasdala  Dieter Grambole  Manfred Wildner  Alexander M. Gigler  Thomas Hainschwang  Alexander M. Zaitsev  Jeffrey W. Harris  Judith Milledge  Daniel J. Schulze  Wolfgang Hofmeister  Walter A. Balmer 《Contributions to Mineralogy and Petrology》2013,165(5):843-861

We have undertaken a study of the common green or orange-brown spots at the surface of rough diamond specimens, which are caused by alpha particles emanating from radioactive sources outside the diamond. Richly coloured haloes represent elevated levels of structural damage, indicated by strong broadening of the main Raman band of diamond, intense strain birefringence, and up-doming of spots due to their extensive volume expansion. Green radio-colouration was analogously generated through the irradiation of diamond with 8.8 MeV helium ions. The generation of readily visible radio-colouration was observed after irradiating diamond with ≥10¹⁵ He ions per cm². The accumulation of such a high number of alpha particles requires irradiation of the diamond from a radioactive source over long periods of time, presumably hundreds of millions of years in many cases. In the samples irradiated with He ions, amorphisation was observed in volume areas where the defect density exceeded 5 × 10^?3 Å^?3 (or 0.03 dpa; displacements per target atom). In contrast, graphitisation as a direct result of the ion irradiation was not observed. The green colouration transformed to brown at moderate annealing temperatures (here 450 °C). The colour transformation is associated with only partial recovery of the radiation damage. The colour change is mainly due to the destruction of the GR1 centre, explained by trapping of vacancies at A defects to form the H3 centre. An activation energy of ~2.4 ± 0.2 eV was determined for the GR1 reduction. The H3 centre, in turn, causes intense yellowish-green photoluminescence under ultraviolet illumination. Radio-colouration and associated H3 photoluminescence are due to point defects created by the ions irradiated, whereas lattice ionisation is of minor importance. This is concluded from the depth distribution of the colouration and the photoluminescence intensity (which corresponds to the defect density but not the ionisation distribution pattern). The effect of the implanted He ions themselves on the colour and photoluminescence seems to be negligible, as radio-colouration and H3 emission were analogously produced through irradiation of diamond with C ions. The photoluminescence emission becomes observable at extremely low defect densities on the order of 10^?6 Å^?3 (or 0.000006 dpa) and is suppressed at moderate defect densities of ~5 × 10^?4 Å^?3 (or ~0.003 dpa). Intensely brown-coloured diamond hence does not show the H3 emission anymore. Anneals up to 1,600 °C has reduced considerably irradiation damage and radio-colouration, but the structural reconstitution of the diamond (and its de-colouration) was still incomplete.  相似文献   

Thermal infrared spectra of experimentally shocked andesine anorthosite     

Jeffrey R. Johnson 《Icarus》2012,221(1):359-364

Andesine-rich (An_36–46) anorthosite rocks experimentally shocked to high pressures (16–57 GPa) exhibit changes in spectral features with increasing pressure in laboratory thermal infrared emission spectra (250–1400 cm^?1). These results are similar to previous studies of shocked bytownite- and albite-rich rocks, albeit with differences in absorption band centers characteristic of mineralogy and composition. Typical spectral absorptions result from Si–O antisymmetric stretch motions of the silica tetrahedral (1000–1250 cm^?1) and weaker absorptions due to Si–O–Si octahedral bending vibrations (350–700 cm^?1). Many of these features persist to higher pressures in the andesine spectra compared to similar features in measurements of shocked bytownite. This is consistent with previous thermal infrared absorption studies of shocked feldspars and likely is related to differences in density, hardness, and Al content. A transparency feature at ～832 cm^?1 observed in powdered andesine spectra also degrades with increasing pressure, intermediate between the ～828 cm^?1 and ～855 cm^?1 transparency features in spectra of powders of shocked bytownite and albitite, respectively. These data can be incorporated into thermal infrared spectral analyses of cratered planetary surfaces (or laboratory spectra of shocked samples) to help constrain the occurrence and degree of shock in plagioclase feldspars.  相似文献   

The site conditions of the Guo Shou Jing Telescope     

Song Yao  Chao Liu  Hao-Tong Zhang  Li-Cai Deng  Heidi Jo Newberg  Yue-Yang Zhang  Jing Li  Nian Liu  Xu Zhou  Jeffrey L. Carlin  Li Chen  Norbert Christlieb  Shuang Gao  Zhan-Wen Han  Jin-Liang Hou  Hsu-Tai Lee  Xiao-Wei Liu  Kai-Ke Pan  Hong-Chi Wang  Yan Xu  Fan Yang 《天体物理学报》2012,(7):772-780

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Hindcasting of tropical cyclone winds and waves     

Zieger  Stefan  Greenslade  Diana J. M.  Aijaz  Saima  Kepert  Jeffrey D.  Burton  Andrew 《Ocean Dynamics》2021,71(5):559-588

Ocean Dynamics - This paper describes a series of hindcast simulations of 17 tropical cyclones over the northwest shelf region of Australia. Tropical cyclone track and vortex details were obtained...  相似文献   

A bio-available strontium isoscape for eastern Beringia: a tool for tracking landscape use of Pleistocene megafauna     

Juliette Funck  Clement Bataille  Jeffrey Rasic  Matthew Wooller 《第四纪科学杂志》2021,36(1):76-90

Numerous paleoecological questions concern the mobility of ancient fauna in eastern Beringia. Strontium (Sr) isotope ratio (⁸⁷Sr/⁸⁶Sr) analysis has emerged as a powerful tracer for determining the provenance of ancient biological materials. However, it is important to characterize ⁸⁷Sr/⁸⁶Sr variation across a landscape. We measured the ⁸⁷Sr/⁸⁶Sr composition of teeth from present-day, herbivorous rodents (n = 162) sampled from across eastern Beringia to estimate bio-available ⁸⁷Sr/⁸⁶Sr values. We compiled these data with the very limited number of previously published ⁸⁷Sr/⁸⁶Sr values from the region. We then used this dataset and a machine learning, random-forest regression to predict bio-available ⁸⁷Sr/⁸⁶Sr variations across eastern Beringia. As a case study using our new ⁸⁷Sr/⁸⁶Sr map (isoscape), we measured the ⁸⁷Sr/⁸⁶Sr and oxygen stable isotope values (δ¹⁸O) of five radiocarbon-dated steppe bison from eastern Beringia and compared these to our ⁸⁷Sr/⁸⁶Sr isoscape and a δ¹⁸O isoscape to estimate the probable landscape use of these ancient fauna. Our model and isoscape provide important foundations for a wide range of additional applications, including studies of the paleo-mobility of other fauna, ancient people and present-day fauna in eastern Beringia.  相似文献   

Improved high-resolution global and regionalized isoscapes of δ18O, δ2H and d-excess in precipitation     

Stefan Terzer-Wassmuth  Leonard I. Wassenaar  Jeffrey M. Welker  Luis J. Araguás-Araguás 《水文研究》2021,35(6):e14254

Patterns of δ¹⁸O and δ²H in Earth's precipitation provide essential scientific data for use in hydrological, climatological, ecological and forensic research. Insufficient global spatial data coverage promulgated the use of gridded datasets employing geostatistical techniques (isoscapes) for spatiotemporally coherent isotope predictions. Cluster-based isoscape regionalization combines the advantages of local or regional prediction calibrations into a global framework. Here we present a revision of a Regionalized Cluster-Based Water Isotope Prediction model (RCWIP2) incorporating new isotope data having extensive spatial coverage and a wider array of predictor variables combined with high-resolution gridded climatic data. We introduced coupling of δ¹⁸O and δ²H (e.g., d-excess constrained) in the model predictions to prevent runaway isoscapes when each isotope is modelled separately and cross-checked observed versus modelled d-excess values. We improved model error quantification by adopting full uncertainty propagation in all calculations. RCWIP2 improved the RMSE over previous isoscape models by ca. 0.3 ‰ for δ¹⁸O and 2.5 ‰ for δ²H with an uncertainty <1.0 ‰ for δ¹⁸O and < 8 ‰ for δ²H for most regions of the world. The determination of the relative importance of each predictor variable in each ecoclimatic zone is a new approach to identify previously unrecognized climatic drivers on mean annual precipitation δ¹⁸O and δ²H. The improved RCWIP2 isoscape grids and maps (season, monthly, annual, regional) are available for download at https://isotopehydrologynetwork.iaea.org .  相似文献   

Speleothem and glacier records of latest Pleistocene–early Holocene climate change in the western North American interior     

Brendon J. Quirk  Glen N. Mackey  Diego P. Fernandez  Andy Armstrong  Jeffrey R. Moore 《第四纪科学杂志》2020,35(6):776-790

Rapid and high-magnitude North Atlantic climate oscillations following the Last Glacial Maximum have been correlated to climate change events in western North America. However, the strength of teleconnections between the North Atlantic and the interior of western North America remains poorly understood. We present a U-series calibrated speleothem record from Timpanogos Cave National Monument, located at 2040 m asl in the Wasatch Mountains of Utah, spanning 13.5–10.6 ka. Additionally, we carried out a climate reconstruction for a coeval glacier advance in the Wind River Range of Wyoming. Our results indicate that between 13.5 and 12.8 ka, the Wasatch was probably first cool and dry and then warmed. After 12.8 ka, our record suggests cool and/or wetter conditions followed by reduced moisture until 11.8 ka, followed by an early Holocene wet period. The Timpanogos record exhibits few similarities with those from the North Atlantic. Climate reconstructions of the Titcomb Basin glacier suggest modest temperature depressions relative to modern (<−3 °C) were necessary to sustain the glacier with a moderate increase in precipitation (>150%). The high-altitude speleothem record presented here provides a valuable basis for understanding latest Pleistocene–early Holocene glacial episodes in western North America.  相似文献   

An island in transition: governing conservation and development in Seram,Indonesia     

James Douglas Langston  Rebecca Anne Riggs  Agni Klintuni Boedhihartono  Agustinus Kastanya  Jeffrey Sayer 《Singapore journal of tropical geography》2020,41(3):413-431

Seram is Indonesia's 8th largest island. It is central to the historic spice islands, once a hotbed for international trade of profitable tree-products, primarily clove and nutmeg. Recent increased rates of social and ecological change, including costly conflicts, present Seram with new challenges and opportunities for conservation and development. Using place-based transdisciplinary research methods, we diagnose the problems emerging in Seram. Engaging with actors across multiple scales and sectors, we explore drivers of change, social-ecological impacts, and institutional arrangements that might achieve improved inclusive and sustainable development outcomes. Traditional and formal governance arrangements require harmonizing to optimize the benefits and costs from large-scale investments arriving in Seram. Organizations wishing to achieve positive impact can more strategically engage with the broad range of actors to harmonize divergent visions for the future and confront the reality of incoming investments and infrastructure.  相似文献   

Active layer hydrology in an arctic tundra ecosystem: quantifying water sources and cycling using water stable isotopes          下载免费PDF全文

Heather M. Throckmorton  Brent D. Newman  Jeffrey M. Heikoop  George B. Perkins  Xiahong Feng  David E. Graham  Daniel O'Malley  Velimir V. Vesselinov  Jessica Young  Stan D. Wullschleger  Cathy J. Wilson 《水文研究》2016,30(26):4972-4986

Climate change and thawing permafrost in the Arctic will significantly alter landscape hydro‐geomorphology and the distribution of soil moisture, which will have cascading effects on climate feedbacks (CO₂ and CH₄) and plant and microbial communities. Fundamental processes critical to predicting active layer hydrology are not well understood. This study applied water stable isotope techniques (δ²H and δ¹⁸O) to infer sources and mixing of active layer waters in a polygonal tundra landscape in Barrow, Alaska (USA), in August and September of 2012. Results suggested that winter precipitation did not contribute substantially to surface waters or subsurface active layer pore waters measured in August and September. Summer rain was the main source of water to the active layer, with seasonal ice melt contributing to deeper pore waters later in the season. Surface water evaporation was evident in August from a characteristic isotopic fractionation slope (δ²H vs δ¹⁸O). Freeze‐out isotopic fractionation effects in frozen active layer samples and textural permafrost were indistinguishable from evaporation fractionation, emphasizing the importance of considering the most likely processes in water isotope studies, in systems where both evaporation and freeze‐out occur in close proximity. The fractionation observed in frozen active layer ice was not observed in liquid active layer pore waters. Such a discrepancy between frozen and liquid active layer samples suggests mixing of meltwater, likely due to slow melting of seasonal ice. This research provides insight into fundamental processes relating to sources and mixing of active layer waters, which should be considered in process‐based fine‐scale and intermediate‐scale hydrologic models. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献